Chemical Communications , 2021, 57 (32), 3905-3908.

Hybrid carbon spherogels: carbon encapsulation of nano-titania

Salihovic, Miralem | Schoiber, Jürgen | Cherevan, Alexey | Rameshan, Christoph | Fritz-Popovski, Gerhard | Ulbricht, Maike | Arnold, Stefanie | Presser, Volker | Paris, Oskar | Musso, Maurizio | Hüsing, Nicola | Elsaesser, Michael S.

Extraordinarily homogeneous, freestanding titania-loaded carbon spherogels can be obtained using Ti(acac)2(OiPr)2 in the polystyrene sphere templated resorcinol-formaldehyde gelation. Thereby, a distinct, crystalline titania layer is achieved inside every hollow sphere building unit. These hybrid carbon spherogels allow capitalizing on carbon's electrical conductivity and the lithium-ion intercalation capacity of titania.

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