Chemical Communications , 2011, 47 (14), 4108-4110.

Facile, fast, and inexpensive synthesis of monodisperse amorphous Nickel-Phosphide nanoparticles of predefined size

Mandel, Karl | Dillon, Frank | Koos, Antal A. | Aslam, Zabeada | Jurkschat, Kerstin | Cullen, Frank | Crossley, Alison | Bishop, Hugh | Moh, Karsten | Cavelius, Christian | Arzt, Eduard | Grobert, Nicole

Monodisperse, size-controlled Ni-P nanoparticles were synthesised in a single step process using triphenyl-phosphane (TPP), oleylamine (OA), and Ni(II)acetyl-acetonate. The nanoparticles were amorphous, contained similar to 30 at% P and their size was controlled between 7-21 nm simply by varying the amount of TPP. They are catalytically active for tailored carbon nanotube growth.