Complexation reactions of titanium tetraethoxide [Ti(OEt)
4
] and titanium tetra-n-butoxide [Ti(OBu
n
)
4
] with 3-pentenoic acid (PA) and allylacetoacetate (AAA), in a 1 : 1M ratio, were studied in ethanol solution at room temperature.
13
C-NMR and FTIR spectra showed that all PA and AAA completely reacted with both titanium alkoxides. Hydridosilane compounds such as triethoxysilane and triethylsilane were added to titanium chelate complexes in a 1 : 1M ratio. The investigation of products by
13
C- and
29
Si-NMR and FTIR showed additions of SiH to the CC double bond. The hydrolysis of titanium-PA and AAA complexes, by water in 1 : 4 ratios, resulted in released PA in an amount of 10% and AAA of 20%. The stability of hydrolyzed products was investigated by
13
C-NMR,
29
Si-NMR, and FTIR.