Energy Materials

The Research Department Energy Materials explores electrochemical materials for sustainable energy storage, innovative water technologies, and eco-friendly recycling solutions.

The Research Department Energy Materials develops materials that can effectively transport and store ions and electrical charges across several length scales. We develop materials that can effectively transport and store ions and electrical charges across several length scales o. Important electrode materials are nanoporous carbons, oxides, carbides, and sulfides, and their hybrids. A key feature is our streamlined workflow from material synthesis, comprehensive structural and chemical material characterization, electrochemical benchmarking, and complementary in situ analysis.

A particular focus is on 2D materials, especially MXene and MBene, to enable rapid charge/discharge supercapacitors and next-next-generation sodium- and lithium-ion batteries. The reversible uptake and controlled release of ions also enables the desalination of seawater and ion separation to separate pollutants such as lead or recover valuable materials such as lithium.

We use various characterization methods, including in situ, for a comprehensive mechanistic understanding. In addition, we are increasingly using digital methods for predictive materials research and digital twinning of battery research. Our collaborations include international basic research as well as industrial projects.

Prof. Dr. Volker Presser
Head of Energy Materials

Kontakt

Deputy Group Leader
M.Sc. Jean Gustavo de Andrade Ruthes
Doctoral Student
Phone: +49 (0)681-9300-218
Laboratory Safety Officer
M.Sc. Zeyu Fu
Technician
Phone: +49 (0)681-9300-368
Secretary
Sylvia de Graaf
Secretary
Phone: +49 (0)681-9300-501
Team Members
Phone: +49 (0)681-9300-151
Phone: +49 (0)681-9300-218
Phone: +49 (0)681-9300-368
Phone: +49 (0)681-9300-108/251
Phone: +49 (0)681-9300-108/251
Phone: +49 (0)681-9300-374
Phone: +49 (0)681-9300-268
Phone: +49 (0)681-9300-374
Phone: +49 (0)681-9300-230
Phone: +49 (0)681-9300-230
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Phone: +49 (0)681-9300-314
Phone: +49 (0)681-9300-402
Phone: +49 (0)681-9300-319
Phone: +49 (0)681-9300-365
Phone: +49 (0)681-9300-365
Phone: +49 (0)681-9300-402
Phone: +49 (0)681-9300-151
Phone: +49 (0)681-9300-108/251
Phone: +49 (0)681-9300-268
Research

Material synthesis

Our team specializes in developing, analyzing, and applying electrochemically active materials and interfaces, focusing on integrating electrochemical activity with electrical conductivity through advanced hybrid materials. We utilize techniques such as sol-gel processes, atomic layer deposition, and electrospinning, supported by comprehensive characterization tools like electron microscopy, X-ray diffraction, and spectroscopy. We extend our work to in situ and in operando methods to deepen our understanding of these materials. Our expertise encompasses a wide array of materials, including carbon and 2D materials like carbon onions and MXene, as well as diverse metal oxides and conversion materials.

Energy storage

Electrochemical energy storage is at the core of sustainable technologies to store, convert, and recover energy. Our research team explores next-generation electrode materials for Sodium- and Lithium-ion batteries, advanced supercapacitors, and novel hybrid systems. A particular focus is on next-next generation electrode materials, including MXene, high-entropy materials, and nanoscaled hybrid materials. We capitalize on an array of synthesis and characterization methods to employ intercalation, conversion reactions, and alloying reactions for boosting the charge storage capacity and charge/discharge rates. Digitalization, digital twinning, and modelling of energy materials and electrode fabrication complements our research portfolio, including basic research and industrial partnerships.

Water technologies

Energy materials are not just prime candidates for electrochemical energy storage but also are gateways to novel water technologies. Via processes much like for batteries and supercapacitors, that is, redox processes (ion intercalation, alloying and conversion reactions) and ion electrosorption, we can manage the flow of ions. We can selectively immobilize and extract specific ions and drive that process not by high pressure or membrane filtration, but by electrochemical processes and ion selective materials. Our key research activities include general seawater desalination, Lithium-ion extraction, and heavy metal ion removal. Our vision is to have electrochemical processes for an array of elements and compounds for energy-efficient deionization toward circular material use, local elemental harvesting, and pollutant removal.

Publications

2022
Ni film decorated on Au-Ag alloy line to enhance graphene/cobalt hydroxide electrodes for micro-supercapacitors

Zhang, Zhiqiang | Xia, Qiuyu | Chen, Yunkai | Pan, Xuexue | Pameté, Emmanuel | Zhang, Yong | Presser, Volker | Abbas, Qamar | Chen, Xinman

Electrochimica Acta , 2022, 433 141247.
https://www.sciencedirect.com/science/article/pii/S0013468622014049

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Electro-assisted removal of polar and ionic organic compounds from water using activated carbon felts

Zhou, Jieying | Zhang, Yuan | Balda, Maria | Presser, Volker | Kopinke, Frank-Dieter | Georgi, Anett

Chemical Engineering Journal , 2022, 433 133544.
https://www.sciencedirect.com/science/article/pii/S1385894721051184

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2021
From capacitive deionization to desalination batteries and desalination fuel cells

Wang, Lei | Zhang, Yuan | Moh, Karsten | Presser, Volker

Current Opinion in Electrochemistry , 2021, 29 100758_1-9.
https://www.sciencedirect.com/science/article/pii/S2451910321000727

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Antimony alloying electrode for high-performance sodium removal: how to use a battery material not stable in aqueous media for saline water remediation

Arnold, Stefanie | Wang, Lei | Budak, Öznil | Aslan, Mesut | Srimuk, Pattarachai | Presser, Volker

Journal of Materials Chemistry A , 2021, 9 (1), 585-596.
http://dx.doi.org/10.1039/D0TA09806J

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Porous Mixed-Metal Oxide Li-Ion Battery Electrodes by Shear-Induced Co-assembly of Precursors and Tailored Polymer Particles

Boehm, Anna K. | Husmann, Samantha | Besch, Marie | Janka, Oliver | Presser, Volker | Gallei, Markus

ACS Applied Materials & Interfaces , 2021, 13 (51), 61166-61179.
https://doi.org/10.1021/acsami.1c19027

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Titanium niobium oxide Ti2Nb10O29/carbon hybrid electrodes derived by mechanochemically synthesized carbide for high-performance lithium-ion batteries

Budak, Öznil | Srimuk, Pattarachai | Aslan, Mesut | Shim, Hwirim | Borchardt, Lars | Presser, Volker

ChemSusChem , 2021, 14 (1), 398-407.
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202002229

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Structural and chemical characterization of MoO2/MoS2triple-hybrid materials using electron microscopy in up to three dimensions

Frank, Anna | Gänsler, Thomas | Hieke, Stefan | Fleischmann, Simon | Husmann, Samantha | Presser, Volker | Scheu, Christina

Nanoscale Advances , 2021, 3 (4), 1067-1076.
http://dx.doi.org/10.1039/D0NA00806K

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Superior Wear-Resistance of Ti3C2TxMultilayer Coatings

Grützmacher, Philipp G. | Suarez, Sebastian | Tolosa, Aura | Gachot, Carsten | Song, Guichen | Wang, Bo | Presser, Volker | Mücklich, Frank | Anasori, Babak | Rosenkranz, Andreas

ACS Nano , 2021, 15 (5), 8216-8224.
https://doi.org/10.1021/acsnano.1c01555

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Molecular Understanding of Charge Storage in MoS2Supercapacitors with Ionic Liquids

Liang, Zhun | Zhao, Chang | Zhao, Wei | Zhang, Yuan | Srimuk, Pattarachai | Presser, Volker | Feng, Guang

ENERGY & ENVIRONMENTAL MATERIALS , 2021, 4 (4), 631-637.
https://onlinelibrary.wiley.com/doi/abs/10.1002/eem2.12147

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In Situ Investigation of Expansion during the Lithiation of Pillared MXenes with Ultralarge Interlayer Distance

Maughan, Philip A. | Arnold, Stefanie | Zhang, Yuan | Presser, Volker | Tapia-Ruiz, Nuria | Bimbo, Nuno

The Journal of Physical Chemistry C , 2021, 125 (38), 20791-20797.
https://doi.org/10.1021/acs.jpcc.1c05092

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