2015, 23 (24), A1642-A1650.

Single-step fabrication process of 1-D photonic crystals coupled to nanocolumnar TiO

González-García, Lola | Colodrero, S. | Míguez, Hernán | González-Elipe, Agustín R.

The present work proposes the use of a TiO

2

electrode coupled to a one-dimensional photonic crystal (1DPC), all formed by the sequential deposition of nanocolumnar thin films by physical vapor oblique angle deposition (PV-OAD), to enhance the optical and electrical performance of DSCs while transparency is preserved. We demonstrate that this approach allows building an architecture combining a non-dispersive 3 µm of TiO

2

electrode and 1 µm TiO

2

-SiO

2

1DPC, both columnar, in a single-step process. The incorporation of the photonic structure is responsible for a rise of 30% in photovoltaic efficiency, as compared with a transparent cell with a single TiO

2

electrode. Detailed analysis of the spectral dependence of the photocurrent demonstrates that the 1DPC improves light harvesting efficiency by both back reflection and optical cavity modes confinement within the TiO

2

films, thus increasing the overall performance of the cell.