2005, 40 (3), 439-446.

Low-temperature synthesis and characterization of yttrium-gallium garnet Y

Mathur, Sanjay | Shen, Hao | Leleckaite, Asta | Beganskiene, Aldona | Kareiva, Aivaras

To obtain yttrium-gallium garnet (Y

3

Ga

5

O

12

, YGG) a simple chimie douce method has been developed. This sol-gel method yielded excellent starting gel precursor for the fabrication of YGG phase, which could be used as host material for optical applications. The pattern of X-ray diffraction analysis of the ceramic sample sintered for 10 h at 1000°C showed the formation of monophasic Y

3

Ga

5

O

12

phase. The phase transformations, composition and micro-structural features in the gels and polycrystalline sample were studied by thermoanalytical methods (TGA/DTA), powder X-ray diffraction analysis (XRD), infrared spectroscopy (IR) and scanning electron microscopy (SEM). The quality of the resulting products (homogeneity, crystallisation temperature, grain size, grain size distribution, etc.) is discussed.